Applications of Equilibrium Constant
Applications of Equilibrium Constant: Overview
This topic covers concepts, such as, Degree of Dissociation for Equilibrium Reactions, Applications of Equilibrium Constants, Predicting Direction of Reaction, Predicting Extent of Reaction & Calculating Composition of Equilibrium Mixture etc.
Important Questions on Applications of Equilibrium Constant
Phosphorus pentachloride dissociates as follows, in a closed reaction vessel,
If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of is , the partial pressure of will be :

moles of and moles of react in a closed vessel. At equilibrium of the is consumed. The total number of gaseous moles in the vessel is:

For the above reaction, vessel contains and moles of and respectively. Then, what will happen to the reaction?

The reaction quotient predicts:

For a reaction products, the value of equilibrium constant , when the reaction reaches completion, would be close to which among the following?

The equilibrium constant for the reaction between and to form and , at is . For the following composition of the reaction mixture, decide which of the following option is correct?

A mixture of and has a vapour density of at . What is the number of moles of in of the mixture?

Column I | Column II |
(A) Equilibrium const. | (p) Reaction will shift forward |
(B) Volume of vessel Equilibrium constant |
(q) Reaction will shift backward |
(C) |
(r) Reaction is in equilibrium |
(D) Helium gas is added to the reaction mixture at equilibrium keeping the pressure constant. |
(s) Reaction may shift in the forward or backward direction. |

The equilibrium constant for the reaction between and to form and , at is . For the following composition of the reaction mixture, decide which of the following option is correct?

Value of for the reaction is 25 at cartain temperature and 4atm pressure.
Initially if we take 2 moles of each of the four gases and 2 moles of inert gas, what would be the equilibrium partial pressure of SO2 ?

Consider the following reaction equilibrium:
Initially in flask mole of and mole of are kept. If equilibrium state the number of moles of , then the total number of moles of all gases present in the flask is


is the degree of dissociation, , , and are the initial pressure, initial temperature, equilibrium pressure and temperature, respectively. What is the value of ?

Consider the following equilibrium in a closed container . Gas at a certain pressure is introduced in the container at . However, the total pressure at equilibrium at was found to be double the initial value. The dissociation of at is:

For the reaction , the correct relationship between degree of dissociation and equilibrium constant is:
equilibrium total pressure

A vessel contains and gases at partial pressures of and , respectively, at a certain temperature the reaction, occurs. It is found that ( represents no. of moles). Identify the correct value of the given property.

At a certain temperature, 2 moles of and 3 moles of were mixed and allowed to reach equilibrium in a vessel according to the reaction .
At equilibrium, if 1 mole of is present, then equilibrium constant for the reaction is:

The above equilibrium is reached in a closed contained initially having dry inert gases. At equilibrium relative humidity of the mixture is . What is if aqueous tension at the same temperature is ?

(gas) decomposes in presence of Helium with total initial pressure of in a closed flask. After of decomposed equilibrium is reached with a net pressure of . What is for

Equilibrium is established in a close container. A very tiny pinhole is made and very-very little amount of equilibrium mixture (equilibrium not altered) is effused out, in which mass percentage of atomic A is . Hence degree of dissociation of is -
